A quantitative study of substituent effects on oxidative cyclization of some 2-aryl-substituted aldehyde thiosemicarbazones induced by ferric chloride and cupric perchlorate

Authors
Noto, R Lo Meo, P Gruttadauria, M Werber, G
Citation
R. Noto et al., A quantitative study of substituent effects on oxidative cyclization of some 2-aryl-substituted aldehyde thiosemicarbazones induced by ferric chloride and cupric perchlorate, J HETERO CH, 36(3), 1999, pp. 667-674
Citations number
23
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF HETEROCYCLIC CHEMISTRY
ISSN journal
0022152X → ACNP
Volume
36
Issue
3
Year of publication
1999
Pages
667 - 674
Database
ISI
SICI code
0022-152X(199905/06)36:3<667:AQSOSE>2.0.ZU;2-9
Abstract
As a development of our previous work, we performed a kinetic study of the oxidative cyclization reaction of some 2,4-diaryl-substituted aldehyde thio semicarbazones 1a-n induced by ferric chloride and by cupric perchlorate. T he results of cyclization of 1a-n were compared to those of the correspondi ng 2-methyl derivatives. The kinetic data were analyzed by means of the Ham mett's equation.