Er. Leite et al., The influence of sintering process and atmosphere on the non-ohmic properties of SnO2 based varistor, J MAT S-M E, 10(4), 1999, pp. 321-327
The non-ohmic properties of the 98.95% SnO2 + 1.0 CoO + 0.05 Nb2O5 (all in
mole%) system, as well as the influence of sintering temperature and atmosp
here on these properties, were characterized in this study. The maximum non
-linear coefficient (alpha = 32) was obtained for a sintering temperature o
f 1300 degrees C in an oxygen atmosphere and this maximum is associated wit
h the presence of O in SnO2 grain boundaries, as interface defects. Experim
ental results also indicate thermionic-type conduction mechanisms, which ar
e associated with the potential barrier of Schottky or Poole-Frenkel types.