Synthesis of the dicarbonyl ruthenium(0) triphosphole complex [Ru(CO)(2){eta(5)-(P3C2Bu2CH)-C-t(SiMe3)(2)}] and its conversion into a tricarbonyl complex containing the novel 4-electron donor triphosphorus-ring system {(CBuPP)-P-t(H)CH(SiMe3)(2)(CBuP)-P-t(O)H}

Authors
Clentsmith, GKB Hitchcock, PB Nixon, JF Sakaraya, N
Citation
Gkb. Clentsmith et al., Synthesis of the dicarbonyl ruthenium(0) triphosphole complex [Ru(CO)(2){eta(5)-(P3C2Bu2CH)-C-t(SiMe3)(2)}] and its conversion into a tricarbonyl complex containing the novel 4-electron donor triphosphorus-ring system {(CBuPP)-P-t(H)CH(SiMe3)(2)(CBuP)-P-t(O)H}, J ORGMET CH, 584(1), 1999, pp. 58-62
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
584
Issue
1
Year of publication
1999
Pages
58 - 62
Database
ISI
SICI code
0022-328X(19990710)584:1<58:SOTDRT>2.0.ZU;2-0
Abstract
1.5-Cyclo-octadiene is readily displaced from [Ru(eta(4)-COD){eta(5)-(P3C2B u2CH)-C-t(SiMe3)(2)}] to give the dicarbonyl complex [Ru(CO)(2){n(5)-(P3C2B u2CH)-C-t(SiMe3)(2)}], which on treatment with water in the presence of CO is converted into a tricarbonyl complex containing the novel 4-electron don or triphosphorus-ring system {(CBuPP)-P-t(H)CH(SiMe3)(2)(CBuP)-P-t(O)H} whi ch has been structurally characterised. (C) 1999 Elsevier Science S.A. All rights reserved.