Novel eta(2)-ring edge coordination in the triphosphaferrocene complex [Fe(eta(5)-C5H5)(eta(5)-(P3C2Bu2)-Bu-t)Rh(eta(5)-C5Me5)CO]

Authors
Callaghan, CSJ Hitchcock, PB Nixon, JF
Citation
Csj. Callaghan et al., Novel eta(2)-ring edge coordination in the triphosphaferrocene complex [Fe(eta(5)-C5H5)(eta(5)-(P3C2Bu2)-Bu-t)Rh(eta(5)-C5Me5)CO], J ORGMET CH, 584(1), 1999, pp. 87-93
Citations number
22
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
584
Issue
1
Year of publication
1999
Pages
87 - 93
Database
ISI
SICI code
0022-328X(19990710)584:1<87:NEECIT>2.0.ZU;2-H
Abstract
Single-crystal X-ray diffraction studies on the triphosphaferrocene [Fe(eta (5)-C5H5)(eta(5)P(3)C(2)'Bu-2)] and its [Rh(eta(5)-C5Me5)CO] complex reveal an unusual eta(2)-ring edge coordination mode in the latter resulting in a significant elongation of the triphosphacyclopentadienyl ring P-P bond. (C ) 1999 Elsevier Science S.A. All rights reserved.