Sf. Son et al., Dynamic observation of a thermally activated structure change in 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) by second harmonic generation, J PHYS CH B, 103(26), 1999, pp. 5434-5440
Using optical second harmonic generation (SHG) we observe, for the first ti
me, a structural change in the energetic material (dry-aminated production
grade) TATB (1,3,5-triamino-2,4,6-trinitrobenzene) upon heating. This struc
ture change is verified by X-ray powder diffraction (XPD). The kinetics of
this structure change are measured and are found to closely match commonly
accepted thermal decomposition parameters for the first step, analogous to
observations made for the beta to delta phase transition in HMX (octahydro-
1,3,5,7-tetranitro-1,3,5,7-tetrazocine). Consequently, these solid structur
e transitions appear to be coupled to the chemical decomposition mechanism
or it may be the first physical process occurring. We apply this technique
as a diagnostic to an ignition experiment. This experiment demonstrates tha
t the structure change can be rapid (it is thermally activated) and that SH
G can be used to indicate not only the solid structure change (large increa
se in SHG intensity) but also the onset to significant decomposition (subse
quent drop in SHG intensity). The ability to selectively change the efficie
ncy of the SHG, in a single piece of explosive, is also demonstrated and ma
y have novel nonlinear optical applications. This application of SHG to TAT
E constitutes a fundamentally new probe in the dynamics of TATE decompositi
on, ignition, and combustion and may have application to optical integrated
devices for frequency conversion and information encoding.