Dispersion of Al2O3 and SIC particles in an alumina sol has been investigat
ed through determination of particle-size distribution, zeta potential, and
agglomerate morphology, The particle size of Al2O3 and SiC (as determined
by the particle-size analyzer) Is strongly affected by the presence of alum
ina sol in the solution, The average agglomerate size is decreased by at le
ast 50%, The zeta potential of Al2O3 in 1M alumina sol increases slightly,
whereas that of SiC reverses its sign over a wide range of pH values. It is
proposed that these effects are caused by AlO4Al12(OH)(24)(H2O)(12)(7+) so
l clusters (1-2 nm In size) that are absorbed on the surface of the large (
1-5 mu m) ceramic particles, The electrostatic and steric effects of the cl
uster absorption help to control the dispersion and stabilize the suspensio
n of ceramic particles in the alumina sol during wet processing, It is expe
cted that the alumina-sol clusters can be used as an efficient, clean dispe
rsant for single-phase and composite ceramic powders.