Single-phase cubic spinel structure MgCr2-xO4 compounds with a controlled M
g/Cr ratio were obtained in stoichiometric composition and Mg excessive reg
ion. All of those single phase samples were p type semiconductor and their
electrical resistivity decreased with increasing the Cr vacancy concentrati
on. This result supports our former conclusion that electrical conduction m
echanism of this system is based on the p-type semiconductor conduction due
to electrical hole by Cr4+.