Transient Raman spectroscopy of isotope-substituted species of bacteriochlorophyll a, bacteriopheophytin a and chlorophyll a: changes in the bond orders in the macrocycles upon triplet and singlet excitation
Y. Koyama et al., Transient Raman spectroscopy of isotope-substituted species of bacteriochlorophyll a, bacteriopheophytin a and chlorophyll a: changes in the bond orders in the macrocycles upon triplet and singlet excitation, LASER CHEM, 19(1-4), 1999, pp. 187-190
The S-0, T-1 and S-1 Raman spectra of bacteriochlorophyll a, bacteriopheoph
ytin a and chlorophyll a were recorded for the species of natural abundance
isotopic composition anti those of totally substituted with N-15, C-13 and
H-2 isotopes. Based on empirical assignments of the Raman lines, changes i
n the bond orders in the macrocycle upon triplet and singlet excitation are
discussed.