Fh. Wang et al., STRENGTHENING OF GLASS RODS AND BOTTLES WITH WATER-BASED EPOXY ACRYLATE COATINGS, Materials science and technology, 13(2), 1997, pp. 163-171
The development of photocured, water based, epoxy acrylate coatings to
negate the deleterious effect surface flaws have on the strength of g
lass is reported. Strengthening of both (a) glass rods that have been
damaged in a controlled fashion and (b) production line bottles is dem
onstrated. In both cases strengthening was achieved whether the coatin
gs were applied by dipping or spraying. The maximum degree of strength
ening was obtained with either a preheat treatment of the coated glass
before a uv cure or a thermal postcure of the coatings. The coating s
ystem included a silane coupling agent to improve the hydrolytic durab
ility of the coatings and the concentration of this coupling agent was
also found to effect the degree of strengthening achieved with the co
atings.