We present ultraviolet (UV) and optical spectropolarimetry of the post-asym
ptotic giant branch star HR 4049 (= HD 89353). The polarization is time-var
iable in both magnitude and position angle. The variations in the polarizat
ion are tied to the orbital period and the circumstellar reddening and, in
the optical, appear to arise from Rayleigh scattering in a thin disc. Howev
er, the ultraviolet (lambda less than or similar to 3000 Angstrom) polariza
tion shows the signature of scattering from material in a bipolar distribut
ion. The near-UV (approximate to 2000-3000 Angstrom) polarization has appro
ximately the same position angle as the optical polarization and hence also
arises from scattering in a disc. However, the component perpendicular to
the disc is of unknown origin. We discuss possible sources for this compone
nt.