M. Benfatto et al., Critical reexamination of the experimental evidence of orbital ordering inLaMnO3 and La0.5Sr1.5MnO4, PHYS REV L, 83(3), 1999, pp. 636-639
The experimental evidence for orbital ordering in LaMnO3 and La0.5Sr1.5MnO4
is critically reexamined in the light of realistic calculations based on m
ultiple scattering theory and finite difference method for the resonant x-r
ay scattered intensity at a forbidden ref lection. It is found that the dip
ole resonant x-ray diffraction at the Mn K-edge is not a suitable technique
for the direct observation of the orbital ordering in the considered compo
unds.