Properties of metal contacts on m-V semiconductors an dependent on the
electronegativity of the metal. Generally metals have been classified
into three categories according to their behaviour upon heat treatmen
t. Au, Ni and W are the three metals belonging to different categories
with the descending order of electronegativity. In this study a low e
nergy position beam has been used to investigate as-grown Au/GaAs (SI)
, Ni/GaAs(SI) and W/GaAs (Sl) samples with different thicknesses of me
tal overlayers. The method that has been employed is that of monitorin
g the Doppler broadening of annihilation radiation through S parameter
measurements as a function of the beam energy. The S-E data were anal
ysed by the program VEPFIT with different models and different implant
ation profiles. It is found that the interfacial information able to b
e extracted from the fitting is limited by present uncertainties in th
e implantation profile.