A new method of synthesizing [Cu(Bipy)(3)](ClO4)(2). Crystal structure revisited and spectral and magnetic characterization

Authors
Pavlishchuk, VV Kalaida, AV Goreshnik, EA
Citation
Vv. Pavlishchuk et al., A new method of synthesizing [Cu(Bipy)(3)](ClO4)(2). Crystal structure revisited and spectral and magnetic characterization, RUSS J C CH, 25(7), 1999, pp. 507-510
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
25
Issue
7
Year of publication
1999
Pages
507 - 510
Database
ISI
SICI code
1070-3284(199907)25:7<507:ANMOS[>2.0.ZU;2-Z
Abstract
Reaction of 2,2'-bipyridyl with malachite in the presence of sodium perchlo rate yields a [Cu(Bipy)(3)](ClO4)(2) complex (I). The compound was characte rized by electronic and TR spectroscopy, and magnetochemical measurements a t room temperature. Crystal structure I was refined by X-ray diffraction an alysis. It was established that the axial Cu-N bond lengths in the [Cu(Bipy )(3)](2+) cation are different, in agreement with the literature data.