The conduction band offset of the type II heterostructure CdS/ZnSe is deter
mined from photoluminescence data of single quantum wells. The cubic quantu
m well samples have been grown by compound-source molecular-beam epitaxy. P
hotoluminescence spectra were measured at low temperatures and evaluated by
fitting an effective mass model to the transition energies. A conduction b
and offset of (0.80 +/- 0.1) eV and an effective electron mass for cubic Cd
S of (0.18 +/- 0.05)m(0) were determined.