The energies of electron and hole polarons in spherical quantum dots based
on materials with a high degree of ionicity are found. It is established th
at consideration of the valence-band degeneracy causes the hole polaron bin
ding energy to be greater than the electron polaron binding energy. The pol
aron effects increase with decreasing quantum dot radius. Interband optical
transitions are accompanied by partial compensation of the polaron effects
, because the emergent electron and hole tend to create polarization potent
ial wells with opposite signs. It is shown that complete compensation of th
e polaron effects does not occur when the valence-band degeneracy is taken
into account. Therefore, interband transitions are accompanied by polarizat
ion of the medium. Such polarization is manifested by the appearance of a s
eries of intense phonon replicas of the lines for the electronic transition
s. (C) 1999 American Institute of Physics. [S1063-7826(99)01507-0].