Hypervalent iodine nitrene precursors bearing N-heterocyclic rings

Authors
Meprathu, BV Diltz, S Walsh, PJ Protasiewicz, JD
Citation
Bv. Meprathu et al., Hypervalent iodine nitrene precursors bearing N-heterocyclic rings, TETRAHEDR L, 40(30), 1999, pp. 5459-5460
Citations number
16
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
30
Year of publication
1999
Pages
5459 - 5460
Database
ISI
SICI code
0040-4039(19990723)40:30<5459:HINPBN>2.0.ZU;2-X
Abstract
Novel nitrene precursors of the form PhINSO2R (R = 1-methylimidazolyl (1), pyridine (2), 2-pyridine N-oxide (3)) have been prepared that contain heter ocyclic sulfonamide residues. These new iodinanes are evaluated as sources of the corresponding heterocycle-containing nitrenes in aziridination and s ulfimidation reactions. (C) 1999 Elsevier Science Ltd. All rights reserved.