A direct route to medium and large cyclic amines from aminoalkenes

Authors
Bergmann, DJ Campi, EM Jackson, WR Patti, AF Saylik, D
Citation
Dj. Bergmann et al., A direct route to medium and large cyclic amines from aminoalkenes, TETRAHEDR L, 40(30), 1999, pp. 5597-5600
Citations number
12
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
30
Year of publication
1999
Pages
5597 - 5600
Database
ISI
SICI code
0040-4039(19990723)40:30<5597:ADRTMA>2.0.ZU;2-J
Abstract
Rhodium-catalysed reactions of aminoalkenes with H-2/CO give cyclic amines with a range of medium and large ring sizes in yields lip to 85%. High regi oselectivity for non-branched products can be obtained when BIPHEPHOS is us ed as a ligand in the hydroformylation reaction. (C) 1999 Elsevier Science Ltd. All rights reserved.