Stereochemistry of alpha-(tert-butoxycarbonylamino) hydroxylamines: H-1 NMR analysis of hydroxylamines derived from 2-pyrrolidinyl nitrones

Authors
Merino, P Franco, S Gascon, JM Merchan, FL Tejero, T
Citation
P. Merino et al., Stereochemistry of alpha-(tert-butoxycarbonylamino) hydroxylamines: H-1 NMR analysis of hydroxylamines derived from 2-pyrrolidinyl nitrones, TETRAHEDR-A, 10(10), 1999, pp. 1861-1865
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
10
Year of publication
1999
Pages
1861 - 1865
Database
ISI
SICI code
0957-4166(19990521)10:10<1861:SOAHHN>2.0.ZU;2-F
Abstract
Hydroxylamines derived from 2-pyrrolidinyl nitrones can be easily and unamb iguously distinguished by H-1 NMR spectroscopy. A strong hydrogen bond whic h can be observed both in the solid state and solution is responsible for t he preferred conformation of the title compounds. (C) 1999 Elsevier Science Ltd. All rights reserved.