Thermo-kinetic research method for faster reactions: modifier method of distorted thermoanalytical curve

Due to the thermal delay of calorimeter, the measured thermoanalytical curv e was distorted. A method to modify the distorted thermoanalytical curve in to the real thermoanalytical curve from which the kinetic parameter can be obtained directly has been established in this paper. The theoretical equat ion for calorimeter, in which the delay of sensing has been considered, and the thermo-kinetic research method for faster reactions, namely the modifi er method of distorted thermoanalytical curve, have been suggested. The the rmo-kinetics. of a few faster reaction systems has been studied with this m ethod and the validity of the theory and method has been verified by the ex perimental results. (C) 1999 Elsevier Science B.V. All rights reserved.