Multicapillary column gas chromatography (MC GC) is presented as a novel te
chnique for the time-resolved sample introduction of gaseous analytes in at
omic spectrometry. The principles and the theory of MC GC, the coupling of
MC GC with microwave-induced plasma atomic emission spectrometry and with i
nductively coupled plasma mass spectrometry, and features of the coupled te
chniques developed are discussed. Applications of MC GC with element-select
ive detection to species-selective analysis are reviewed. The possibility o
f incorporating MC columns into dedicated sample preparation accessories fo
r elemental speciation by atomic spectrometry is evaluated. (C) 1999 Elsevi
er Science B.V. All rights reserved.