Preparation and crystal structure of triammonium-trisulfimid (NH4)(3)(NSO2)(3)

Authors
Leben, C Jansen, M
Citation
C. Leben et M. Jansen, Preparation and crystal structure of triammonium-trisulfimid (NH4)(3)(NSO2)(3), Z NATURFO B, 54(6), 1999, pp. 757-760
Citations number
15
Categorie Soggetti
Chemistry
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
ISSN journal
09320776 → ACNP
Volume
54
Issue
6
Year of publication
1999
Pages
757 - 760
Database
ISI
SICI code
0932-0776(199906)54:6<757:PACSOT>2.0.ZU;2-4
Abstract
The preparation and crystal structure of (NH4NSO2)(3) (a = 11.720(2), b = 6 .156(6), c = 14.030(2) Angstrom,beta = 96.69(8)degrees) is reported. The st ructure reveals a chair-conformation of the anions, which are arranged to f orm a hexagonal rod stacking. Compared to cyclometatriphosphates the cation s are coordinated differently due to the different basicities of the bridgi ng nitrogen and oxygen atoms, respectively.