Trace metal determination by de resistance changes of microstructured thingold film electrodes

The deposition of adatoms onto the surface of a thin metal film can increas e its lateral dc resistance. The magnitude of the increase is related to th e surface coverage. We have utilized this phenomenon for the determination of heavy metal concentrations in aqueous solution, Using thin gold films as working electrodes ina three electrode arrangement, we deposited cadmium, lead, nickel, thallium and zinc ions as well as Cd-EDTA complexes and measu red the corresponding resistance changes. Different species could be distin guished from each other. For cadmium ions a linear relationship between the induced resistance change and the cadmium concentration has been achieved over a concentration range between 4 ng/g and 1 mu g/g. (C) 1999 Elsevier S cience Ltd. All rights reserved.