I. Poulios et I. Aetopoulou, Photocatalytic degradation of the textile dye Reactive Orange 16 in the presence of TiO2 suspensions, ENV TECHNOL, 20(5), 1999, pp. 479-487
The photocatalytic degradation of Reactive Orange 16, a textile azo dye, ha
s been investigated in aqueous heterogeneous solutions containing titanium
dioxide TiO2 as photocatalyst. The disappearance of the organic molecule fo
llows approximately a pseudo-first kinetic order according to the Langmuir-
Hinshelwood model. CO2, NO3; NH4+ and SO42- ions have been identified as mi
neralization products. Various commercial photocatalysts were compared with
respect to their decolorization efficiency, as well as the production of C
O2. The effect of pH and H2O2 on the reaction rate was ascertained.