Synthesis and characterization of dioxo-molybdenum(VI) and oxomolybdenum(V) complexes of salicylaldehyde morpholine N-thiohydrazone (H(2)smth) and 2-hydroxyacetophenone morpholine N-thiohydrazone (H(2)apmth)

Authors
Dey, K Chakraborty, K
Citation
K. Dey et K. Chakraborty, Synthesis and characterization of dioxo-molybdenum(VI) and oxomolybdenum(V) complexes of salicylaldehyde morpholine N-thiohydrazone (H(2)smth) and 2-hydroxyacetophenone morpholine N-thiohydrazone (H(2)apmth), I J CHEM A, 38(4), 1999, pp. 381-384
Citations number
30
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
4
Year of publication
1999
Pages
381 - 384
Database
ISI
SICI code
0376-4710(199904)38:4<381:SACODA>2.0.ZU;2-W
Abstract
A few dioxomolybdenum(VI) and oxomolybdenum(V) complexes have been synthesi sed with tridentate NSO donor hydrazone ligands derived by the condensation of morpholine N-thiohydrazide with salicylaldehyde and 2-hydroxyacetopheno ne. The complexes, have been characterized by elemental analyses, molecular weights, magnetic moments, molar conductances, infrared and electronic spe ctral data The ligands are found to act in dibasic tridentate fashion.