Indirect micellar spectrophotometric determination of cyanide ions throughligand exchange reaction in solution

Authors
Garg, BS Bhojak, N Dwivedi, P Bist, JS Aggarwal, MB
Citation
Bs. Garg et al., Indirect micellar spectrophotometric determination of cyanide ions throughligand exchange reaction in solution, I J CHEM A, 38(4), 1999, pp. 395-397
Citations number
23
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
4
Year of publication
1999
Pages
395 - 397
Database
ISI
SICI code
0376-4710(199904)38:4<395:IMSDOC>2.0.ZU;2-#
Abstract
The decomposition of silver(I)-NTHB complex in the Triton X-100 micellar me dium by cyanide ions takes place instantaneously and this has been used to develop a sensitive, convenient and rapid indirect micellar spectrophotomet ric method for the determination of cyanide ions. The calibration graph is linear over the range 0.10-0.90 mu g/ml of cyanide. The method is relativel y free from interference and satisfactorily applied for the determination o f cyanide in synthetic samples with a coefficient of variation less than 1% .