A morphology study in films of polyethylene oxide (PEO) complexed with ammo
nium perchlorate (NH4ClO4) is presented. Wide variety of structures were ob
tained by varying salt concentration from x = 0 - 0.35 (where x is the weig
ht fraction of the salt, NH4ClO4). The transition in morphology is studied
in detail by photography and optical microscopy. Variable temperature polar
ising microscopy was also done to identify the individual phases present in
the films.