Laser-based in situ diagnostic techniques with high temporal, spectral, and
spatial resolution have become valuable tools to study the molecular dynam
ics of gas-phase and heterogeneous reactions as well as complex technical c
ombustion processes. Results of recent experiments will be presented in whi
ch laser-induced fluorescence, sum-frequency generation surface vibrational
spectroscopy, Rayleigh scattering, excimer laser-induced fragmentation flu
orescence, and high-resolution tunable diode laser absorption spectroscopy
a ere applied to investigate elementary chemical gas-phase and catalytic co
mbustion reactions, internal combustion engine processes, as well as coal c
ombustion and waste incineration.