The potent odorants of standardized, enzymatically hydrolyzed, and deoiled
soybean lecithins were characterized systematically by combined gas chromat
ography/mass spectrometry and olfactometry. Sixty-one odorants were identif
ied; 53 of these odor-active compounds have not previously been reported as
odorants of soybean lecithin flavor. By aroma extract dilution analysis an
d modified combined hedonic and response measurement the following odorants
showed the highest flavor dilution factors and CHARM values: (E,E)-2,4-dec
adienal (deep-fried), (E)-beta-damascenone (apple-like), 2,3-diethyl-5-meth
ylpyrazine (roasty, earthy), (E)-2-nonenal (cardboard-like), trans-4,5-epox
y-(E)-2-decenal (metallic), 1-nonen-3-one (mushroom-like), 2-ethyl-3,5-dime
thylpyrazine (roasty, earthy), and 1-octen-3-one (mushroom-like). Enzymatic
hydrolysis intensified especially the roasty sensation of 2,3-diethyl-5-me
thylpyrazine, whereas deoiling effected a general significant decrease in o
lfactory perception on the nitrogen-containing compounds. In addition, sens
ory profiles of nasal and retronasal lecithin odor were performed.