Synthesis and crystal structure of (+)-(2R,3R)-N, N '-bis-trityl-2,3-bis-aziridine

Authors
Buijnsters, PJJA van der Reijden, FP Feiters, MC de Gelder, R Sommerdijk, NAJM Nolte, RJM Zwanenburg, B
Citation
Pjja. Buijnsters et al., Synthesis and crystal structure of (+)-(2R,3R)-N, N '-bis-trityl-2,3-bis-aziridine, J CHEM CRYS, 29(2), 1999, pp. 179-183
Citations number
32
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
2
Year of publication
1999
Pages
179 - 183
Database
ISI
SICI code
1074-1542(199902)29:2<179:SACSO(>2.0.ZU;2-Q
Abstract
A new C-2 symmetric bis-aziridine derivative was synthesized starting from L-(+)-tartaric acid. The molecular structure of (+)-(2R, 3R)-N, N'-bis-trit yl-2,3-bis-aziridine 4, was determined by H-1, C-13 NMR and elemental analy sis and was confirmed by single-crystal X-ray diffraction. Crystal data for 4: C42H36N2, orthorhombic, space group: P2(1)2(1)2(1), a = 12.7633(14), b = 14.5661(6), c = 17.4184(14) Angstrom, and Z = 4.