Structure of (2,2'-bipyridine)lead(II) saccharinate monohydrate

Authors
Jovanovski, G Hergold-Brundic, A Grupce, O Matkovic-Calogovic, D
Citation
G. Jovanovski et al., Structure of (2,2'-bipyridine)lead(II) saccharinate monohydrate, J CHEM CRYS, 29(2), 1999, pp. 233-237
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
2
Year of publication
1999
Pages
233 - 237
Database
ISI
SICI code
1074-1542(199902)29:2<233:SO(SM>2.0.ZU;2-1
Abstract
The structure of (2,2'-bipyridine)lead(II) saccharinate monohydrate has bee n investigated by X-ray diffraction. The compound crystallizes in the monoc linic space group P2(1)/n with a = 22.903(7), b = 12.608(3), c = 8.682(2) A ngstrom, beta = 96.76(3)degrees, and Z = 4. The structure consists of Pb2cations, 2,2'-bipyridine ligands, saccharinato anions and water molecules. The Pb2+ cation is surrounded by two O atoms and four N atoms. The two sacc harinato ions are nonequivalent. The water molecule forms hydrogen bonds of O-W... O-CO [2.810(16) Angstrom] and O-W... O-SO2 [2.893(16) Angstrom] typ e.