D. Swenson, Phase equilibria in In-metal-As systems: Systematic trends in phase diagram topology and implications for the development of contact materials to InAs, J ELEC MAT, 28(7), 1999, pp. 894-901
Isothermal phase equilibria are established in the InAs-rich regions of 16
In-M-As ternary systems, where "M" denotes a transition or noble metal. The
se new data, combined with work previously reported in the literature, prov
ide a nearly complete picture of phase equilibria in In-M-As systems. The t
opologies of the In-M-As phase diagrams are found to vary systematically ac
cording to the position of M in the periodic table. This correlation may be
rationalized using experimental thermodynamic data found in the literature
, and reflects a systematic dependency of the relative thermodynamic stabil
ities of transition and noble metal indides and arsenides on atomic number
of the metal. These phase diagram data are also utilized to select material
s that are suitable as contact metallizations to InAs. Based on the criteri
a of thermodynamic equilibrium, ease of fabrication, and high melting point
, W, Re, Os, RhIn3, PdIn and PtIn2 are identified as the most promising pot
ential contact materials to InAs.