P. Laakkonen et al., Multilevel diffractive elements in SiO2 by electron beam lithography and proportional etching with analogue negative resist, J MOD OPT, 46(8), 1999, pp. 1295-1307
A negative low-contrast electron beam resist X AR-N 7700/18 is introduced,
which provides a nearly linear dose-to-depth curve at electron acceleration
voltages below 20kV, and is therefore an excellent material for fabricatio
n of multilevel diffractive optics. Direct electron beam recording at 12.5
kV is used to pattern analogue surface profiles in this resist, and proport
ional reactive ion etching (RIE) is employed to transfer the profile into t
he SiO2 substrate. It is shown that errors in resist-profile scale can be c
orrected by proper adjustment of the radio-frequency power or chamber press
ure in RIE. The reproducibility of the profile scale is better than 2%. Tra
nsmission-type blazed gratings, array illuminators, and pattern projection
elements are demonstrated.