Optical spectroscopy methods are used to study the spectra of some oxygen-o
ctahedral ferroelectrics-namely LiNbO3 and LiTaO3. It is shown that for the
measured range of E and T, alpha varies exponentially with the photon ener
gy following the empirical Urbach rule. A study of the role of the BO6-octa
hedron by using spectroscopic methods can cast light on the many physical p
henomena that take place in LiNbO3 and LiTaO3. For these crystals, absorpti
on edge, band gap, Urbach constants and phonon energy are found.