Relativistic effects in photoabsorption of the outer atomic shells

Citation
Bm. Lagutin et al., Relativistic effects in photoabsorption of the outer atomic shells, J STRUCT CH, 39(6), 1998, pp. 811-818
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
39
Issue
6
Year of publication
1998
Pages
811 - 818
Database
ISI
SICI code
0022-4766(199811/12)39:6<811:REIPOT>2.0.ZU;2-E
Abstract
Photoionization cross sections and angular electron distribution parameters in the photoionization of the subvalent shells of Kr and Xe atoms are calc ulated. The configuration interaction theory and the perturbation theory ar e used for describing the many-electron effects. Relativistic effects are t aken into account in the Pauli-Fock approximation. The necessity is shown t o take into account simultaneously many-electron and relativistic effects i n the description of the photoionization of the outer shells in the near-th reshold region.