Conversion spectra of valence shell electrons of oxygen-containing uraniumcompounds

Authors
Panov, AD Zhudov, VI Teterin, YA
Citation
Ad. Panov et al., Conversion spectra of valence shell electrons of oxygen-containing uraniumcompounds, J STRUCT CH, 39(6), 1998, pp. 858-862
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
39
Issue
6
Year of publication
1998
Pages
858 - 862
Database
ISI
SICI code
0022-4766(199811/12)39:6<858:CSOVSE>2.0.ZU;2-M
Abstract
The structure of the experimental conversion spectra of an ultrasoft nuclea r isomer transition of uranium-235 in oxygen-containing uranium compounds i s investigated quantitatively. The behavior of the intensity of the U6p(1/2 ) line in the spectrum is analyzed. It is established that the quasiatomic U6p(1/2) orbital in uranyl compounds retains (69+/-9)% primary electron den sity on the uranium atom, the remainder passing to molecular orbitals.