Dynamic effect on the structure of X-ray photoelectron spectra of lanthanide fluorides and oxides

Citation
Ya. Teterin et al., Dynamic effect on the structure of X-ray photoelectron spectra of lanthanide fluorides and oxides, J STRUCT CH, 39(6), 1998, pp. 869-875
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF STRUCTURAL CHEMISTRY
ISSN journal
00224766 → ACNP
Volume
39
Issue
6
Year of publication
1998
Pages
869 - 875
Database
ISI
SICI code
0022-4766(199811/12)39:6<869:DEOTSO>2.0.ZU;2-Z
Abstract
Dynamic effect on the fine structure of X-ray photoelectron spectra of lant hanide oxides and fluorides is discussed. The Ln4p electron spectra are con siderably complicated by the interaction between the configurations of the main one-hole and additional two-hole final states of 4p (5)4d (10)4f(n) <- > 4p (6)4d (8)4f(n+1) type. The effect of the nature of atoms in the neares t environment of lanthanide ions on the fine structure parameters is evalua ted.