Native vacancies in Te-doped (5x10(16)-5x10(18) cm(-3)) GaAs were investiga
ted by means of position lifetime and Doppler-broadening coincidence spectr
oscopy. The experimental data were related to theoretical calculations of t
he positron lifetime and the annihilation momentum distribution. Monovacanc
ies were observed in all Te-doped GaAs samples under study. It will be show
n that they can directly be identified to be Ga-vacancy-Te-As-donor complex
es. These complexes are the dominating type of vacancy defects in the dopin
g range under observation. [S0163-1829(99)07327-0].