The band structure of the cubic spinel compound LiV2O4, which has been repo
rted recently to show heavy Fermion behavior, has been calculated within th
e local-density approximation using a full-potential version of the linear
augmented-plane-wave method. The results show that partially filled V 3d ba
nds are located about 1.9 eV above the O 2p bands and the V 3d bands are sp
lit into a lower partially filled t(2g) complex and an upper unoccupied e(g
) manifold. The fact that the conduction electrons originate solely from th
e t(2g) bands suggests that the mechanism for the mass enhancement in this
system is different from that in the 4f heavy Fermion systems, where these
effects are attributed to the hybridization between the localized 4f levels
and itinerant s p d bands.