Citation
M. Sangermano et al., Cationic photopolymerisation of divinylethers systems containing hydroxyvinylethers, POLYM BULL, 42(6), 1999, pp. 641-648
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER BULLETIN
ISSN journal
01700839
→ ACNP
Volume
42
Issue
6
Year of publication
1999
Pages
641 - 648
Database
ISI
SICI code
0170-0839(199907)42:6<641:CPODSC>2.0.ZU;2-O
Abstract
Diethyleneglycoldivinylether (DVE2) and triethyleneglycoldivinylether (DVE3
) were photopolymerised together with monovinylethers and hydroxyalkylvinyl
ethers, in order to study the curing reaction and to evaluate the propertie
s of the films obtained. In the presence of the monovinylethers, the flexib
ility of the cured films increased and the Tg values decreased. In the pres
ence of a hydroxyalkylvinyl ether, a stronger plasticisation effect was obt
ained and attributed to a chain transfer reaction involving -OH groups.