Isomerism of copper(II) coordination compounds with hydroxamic acids

Authors
Larin, GM Rotov, AV Dzyuba, VI
Citation
Gm. Larin et al., Isomerism of copper(II) coordination compounds with hydroxamic acids, RUSS CHEM B, 48(4), 1999, pp. 722-725
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
4
Year of publication
1999
Pages
722 - 725
Database
ISI
SICI code
1066-5285(199904)48:4<722:IOCCCW>2.0.ZU;2-3
Abstract
The structure of Cu-II complexes with hydroxamic acids Cu[(RN)-N-1(O)-(O)CR 2](2), where R-1 = Ph, R-2 = Me; R-1 = Me, R-2 = Ph, was studied by ESR spe ctroscopy. In toluene solutions and low-temperature glasses, the complexes exist as two forms, which were identified as cis- and trans-isomers. The pr oportions of the isomers were determined.