Synthesis and transformations of metallocycles 19. Synthesis of 3-alkylalumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes on Zr-containing complex catalysts

Authors
Ibragimov, AG Khafizova, LO Yakovleva, LG Nikitina, EV Satenov, KG Khalilov, LM Dzhemilev, UM
Citation
Ag. Ibragimov et al., Synthesis and transformations of metallocycles 19. Synthesis of 3-alkylalumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes on Zr-containing complex catalysts, RUSS CHEM B, 48(4), 1999, pp. 774-780
Citations number
12
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
4
Year of publication
1999
Pages
774 - 780
Database
ISI
SICI code
1066-5285(199904)48:4<774:SATOM1>2.0.ZU;2-B
Abstract
A regioselective method for the synthesis of 3-alkyialumacyclopentanes and 2-alkyl-1,4-dialuminiobutanes by the reactions of alpha-olefins with EtAlCl 2, ROAlCl2, R2NAlCl2, or Et2AlCl and the Mg-ClCH2CH2Cl-Cp2ZrCl2 (ZrCl4) sys tem was developed.