C-13, N-15, and O-18 equilibrium isotope effects and fractionation factors

Authors
Rishavy, MA Cleland, WW
Citation
Ma. Rishavy et Ww. Cleland, C-13, N-15, and O-18 equilibrium isotope effects and fractionation factors, CAN J CHEM, 77(5-6), 1999, pp. 967-977
Citations number
48
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
77
Issue
5-6
Year of publication
1999
Pages
967 - 977
Database
ISI
SICI code
0008-4042(199905/06)77:5-6<967:CNAOEI>2.0.ZU;2-7
Abstract
A listing of C-13, N-15, and O-18 equilibrium isotope effects and fractiona tion factors for atoms in specific positions is provided. Empirical factors that can be used to adjust these fractionation factors for more complex st ructures are presented and discussed. While much work needs to be done to d etermine equilibrium-isotope effects for these heavy atoms, the values tabu lated here should be useful to anyone working with isotope effects involvin g these atoms.