New hyperfine-decoupling schemes in electron paramagnetic resonance spectroscopy

Authors
Van Doorslaer, S Schweiger, A
Citation
S. Van Doorslaer et A. Schweiger, New hyperfine-decoupling schemes in electron paramagnetic resonance spectroscopy, CHEM P LETT, 308(3-4), 1999, pp. 187-194
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
308
Issue
3-4
Year of publication
1999
Pages
187 - 194
Database
ISI
SICI code
0009-2614(19990723)308:3-4<187:NHSIEP>2.0.ZU;2-2
Abstract
Two new hyperfine-decoupling schemes for electron spin echo envelope modula tion (ESEEM) experiments, namely the hyperfine-decoupled combination-peak e xperiment (DECOM) and hyperfine-decoupled DEFENCE (deadtime free ESEEM by n uclear coherence-transfer echoes), are proposed. The two techniques are com pared with known hyperfine-decoupling schemes and nuclear Zeeman-resolved E SEEM. The advantages of the new approaches are experimentally demonstrated in three applications. (C) 1999 Published by Elsevier Science B.V. All righ ts reserved.