Rotational line profile in the He I excited photoelectron spectrum of the (XB1)-B-2 [upsilon '=(0,0,0)] state of H2O+

Authors
Ohrwall, G Baltzer, P
Citation
G. Ohrwall et P. Baltzer, Rotational line profile in the He I excited photoelectron spectrum of the (XB1)-B-2 [upsilon '=(0,0,0)] state of H2O+, CHEM P LETT, 308(3-4), 1999, pp. 199-203
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
308
Issue
3-4
Year of publication
1999
Pages
199 - 203
Database
ISI
SICI code
0009-2614(19990723)308:3-4<199:RLPITH>2.0.ZU;2-U
Abstract
A photoelectron spectrum of the (XB1)-B-2[v' = (0,0,0)] state of H2O+ has b een recorded, excited with He I radiation. The line profile exhibits extens ive rotational structure, and a simple analysis based on the ground-state r otational population is used to interpret the spectrum. Judging from this a nalysis, c-type transitions account for the dominant part of the intensity. (C) 1999 Elsevier Science B.V. All rights reserved.