The complete dynamics of internal hindered rotations and torsion modes of t
etratomic molecules is recovered in the framework of an algebraic approach.
This model is capable of providing detailed information for torsion/tunnel
and bending levels in a semi-rigid approximation, with special emphasis on
intramolecular interaction terms rather than on the construction of effect
ive potential functions. We show the most important features of this method
by considering as a case study the description of torsion bands in H2O2. (
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