Preparation and chromatographic characteristics of calix[4]arene polysiloxane as stationary phases for capillary gas chromatography

Authors
Lai, XH Lin, L Wu, CY
Citation
Xh. Lai et al., Preparation and chromatographic characteristics of calix[4]arene polysiloxane as stationary phases for capillary gas chromatography, CHROMATOGR, 50(1-2), 1999, pp. 82-88
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Spectroscopy /Instrumentation/Analytical Sciences
Journal title
CHROMATOGRAPHIA
ISSN journal
00095893 → ACNP
Volume
50
Issue
1-2
Year of publication
1999
Pages
82 - 88
Database
ISI
SICI code
0009-5893(199907)50:1-2<82:PACCOC>2.0.ZU;2-9
Abstract
Two new kinds of calix[4]arene derivatives, 5,11,17,23-tetra- tert-butyl-25 ,27-bis(isopropylcarbamoyl-methoxy)-26,28-diundecenyloxy calix[4]arene (C[4 ]A) and 25,27-dibutoxy-5,11,17,23-tetra-tert-butyl-26,28-diundecenyloxy cal ix[4]arene (C[4]B), are prepared and then are polymerized by two different processes. Three calix[4]arene polysiloxane stationary phases for capillary gas chromatography are obtained. Their chromatographic characteristics, in cluding column efficiency, polarity, selectivity, glass-transition temperat ure and thermal stability are studied. Retention mechanisms are also discus sed.