B. Stibr et al., Oxidation of the [nido-6,9-C2B8H10](2-) anion - An alternative source of the 1,6-and 1,10-dicarba-closo-decaboranes(10), COLL CZECH, 64(6), 1999, pp. 971-976
Citations number
17
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
The oxidation of the [nido-6,9-C2B8H10](2-) (1) dianion with CuCl2, is supp
osed to proceed via an unstable closo-2,6-C2B8H10 (2) intermediate, which i
s then rearranged into closo-1,6-C2B8H10 (3) (yields 30-35%). The synthesis
is accompanied by the formation of the isomeric closo-dicarbaboranes 1,10-
C2B8H10 (4) and 1,2-C2B8H10 (5) and the whole procedure can be modified to
isolate only isomer 4 (yield 35%). Side products from the synthesis consist
of a complex and so far unseparable mixture, in which arrrchno-4,6-C2B7H13
, chloro derivatives closa-C2B8H9Cl, and trimeric compounds of a closo-(C2B
8H9)(2)-C2B8H8 formulation were detected by GLC/MS techniques. These findin
gs point to the involvement of a radical-chain mechanism in the reaction.