Determination of several thermophysical properties of toluene using a single experimental setup

Dynamic light scattering can be used for the determination of several therm ophysical properties of interest using one single experimental setup. Light scattering from bulk fluids allows the measurement of thermal diffusivity and sound velocity. Results are presented for toluene, an important referen ce fluid, over a wide temperature range up to the critical point at saturat ion conditions for both the liquid and the vapour phase. Furthermore, it is demonstrated that the same setup can be used for the determination of surf ace tension and kinematic viscosity of the liquid phase from light scatteri ng by surface waves on a vertical liquid layer. All experiments are based o n a heterodyne detection scheme and signal analysis by photon correlation s pectroscopy. The results are discussed in comparison with literature data. (C) 1999 Elsevier Science B.V. All rights reserved.