Chemistry of silyl thioketones: Studies concerning the regiochemistry of the cycloaddition with substituted 1,3-dienes

Citation
Bf. Bonini et al., Chemistry of silyl thioketones: Studies concerning the regiochemistry of the cycloaddition with substituted 1,3-dienes, HETEROCYC C, 5(3), 1999, pp. 217-226
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLIC COMMUNICATIONS
ISSN journal
07930283 → ACNP
Volume
5
Issue
3
Year of publication
1999
Pages
217 - 226
Database
ISI
SICI code
0793-0283(1999)5:3<217:COSTSC>2.0.ZU;2-9
Abstract
The cycloaddition between a series of silyl thioketones and substituted, op en-chain 1,3-dienes was investigated: mixtures of regioisomeric 5,6-dihydro (2H) thiopyrans are formed. The structures of the major isomers were assig ned on the basis of both spectroscopic analysis and chemical correlations.