A supramolecular synthon for H-bonded transition metal arrays

Authors
Bernhardt, PV
Citation
Pv. Bernhardt, A supramolecular synthon for H-bonded transition metal arrays, INORG CHEM, 38(15), 1999, pp. 3481-3483
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
38
Issue
15
Year of publication
1999
Pages
3481 - 3483
Database
ISI
SICI code
0020-1669(19990726)38:15<3481:ASSFHT>2.0.ZU;2-M
Abstract
The heterocycle melamine appended to a 14-membered polyazamacrocyclic coppe r(II) complex ring exhibits a strong propensity for ordered arrays driven b y H-bonding forces. In this work, the X-ray crystal structures of three dis tinctly different arrays based on the same macrocyclic complex are reported , comprising cocrystals with barbituric acid (a sheet structure) and cyanur ic acid (a linear chain) and the parent complex (a linear tape).